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Exfoliated Nanosheets of Graphitic Carbon Nitride: Study of Optical and Photoectrochemical Properties

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27360%2F17%3A86100571" target="_blank" >RIV/61989100:27360/17:86100571 - isvavai.cz</a>

  • Alternative codes found

    RIV/61989100:27710/17:86100571

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Exfoliated Nanosheets of Graphitic Carbon Nitride: Study of Optical and Photoectrochemical Properties

  • Original language description

    The graphitic carbon nitride (g-C3N4) samples were prepared by the three different methods: (i) heating of melamine at 600 ºC (bulk g-C3N4), (ii) exfoliation of bulk g-C3N4 by heating at 500 ºC (Ex500) and (iii) exfoliation of bulk g-C3N4 by ultrasonication in an aqueous dispersion (ExUltra). The exfoliation was performed to obtain g-C3N4 nanosheets or other nanostructures. The samples characterization was performed by UV-Vis diffuse reflectance (DRS UV-Vis), photoluminescence (PL) spectroscopy and photoelectrochemical (PEC) measurement. The smallest transition energies Et was evaluated for bulk g-C3N4 (Et = 2.84 eV). The exfoliation by heating and ultrasonication caused both increase of transition energies Et at 3.07 eV and blue-shift and intensity increase of PL emission bands. The exfoliation by heating at 500 ºC increased photocurrent in comparison with the bulk g-C3N4 and ultrasonicated samples. This indicates the beneficial effect of the exfoliation by heating for various photocatalytic applications due to the higher mobility and separation efficiency of photo-induced carriers.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

  • OECD FORD branch

    20501 - Materials engineering

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2017

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    NANOCON 2016: 8th International Conference on Nanomaterials - Research &amp; Application : list of abstracts : October 19th-21st 2016, Hotel Voronez I, Brno, Czech Republic, EU

  • ISBN

    978-80-87294-68-0

  • ISSN

  • e-ISSN

    neuvedeno

  • Number of pages

    6

  • Pages from-to

    98-103

  • Publisher name

    Tanger

  • Place of publication

    Ostrava

  • Event location

    Brno

  • Event date

    Oct 19, 2016

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article

    000410656100016