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Composites of BiVO4 and g-C3N4: Synthesis, Properties and Photocatalytic Decomposition of Azo Dye AO7 and Nitrous Oxide

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27360%2F19%3A10242125" target="_blank" >RIV/61989100:27360/19:10242125 - isvavai.cz</a>

  • Alternative codes found

    RIV/61989100:27710/19:10242125 RIV/61989100:27740/19:10242125 RIV/44555601:13440/19:43894636

  • Result on the web

    <a href="https://doi.org/10.1007/s10904-019-01085-4" target="_blank" >https://doi.org/10.1007/s10904-019-01085-4</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s10904-019-01085-4" target="_blank" >10.1007/s10904-019-01085-4</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Composites of BiVO4 and g-C3N4: Synthesis, Properties and Photocatalytic Decomposition of Azo Dye AO7 and Nitrous Oxide

  • Original language description

    The composites of BiVO4 and g-C3N4 (BiVO4/g-C3N4) were synthesised by the calcination of a mixture of monoclinic BiVO4 and bulk g-C3N4 at 300 oC for 4 h. Both components were previously prepared by the precipitation of Bi(NO3)3 with NH4VO3 and annealing of melamine. X-ray photoelectron spectroscopy identified the presence of C-O and C=O bonds as well as metal nitrides which confirmed the formation of a heterojunction between BiVO4 and g-C3N4. The heterojunction was also indicated by UV-Vis diffuse reflectance and photoluminescence spectroscopy. The band gap energies were determined at 2.42-2.46 eV of BiVO4 and 2.75-2.82 eV of bulk g-C3N4. The specific surface area was 23-28 m2g-1 of the composites and 6 m2g-1 and 35 m2g-1 of pure BiVO4 and g-C3N4, respectively. The photocatalytic activity of the composites was investigated by the decomposition of Acod Orange 7 (AO7) and nitrous oxide. In case of AO7, the BiVO4/g-C3N4 (1:3) composite was the most active one and the main role in the reaction was played by photoinduced holes forming hydroxyl radicals. At the decomposition of N2O, the most important species were the photoinduced electrons and the BiVO4/g-C3N4 (1:1) composite was the most active photocatalyst.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20505 - Composites (including laminates, reinforced plastics, cermets, combined natural and synthetic fibre fabrics; filled composites)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Inorganic and Organometallic Polymers and Materials

  • ISSN

    1574-1443

  • e-ISSN

  • Volume of the periodical

    29

  • Issue of the periodical within the volume

    4

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    16

  • Pages from-to

    1219-1234

  • UT code for WoS article

    000471198700018

  • EID of the result in the Scopus database