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Recycling of fly ash and carbide slag in low-carbon cement composites by pre-depolymerization and pre-dissolution treatment

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27360%2F24%3A10256345" target="_blank" >RIV/61989100:27360/24:10256345 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S235271022402970X" target="_blank" >https://www.sciencedirect.com/science/article/pii/S235271022402970X</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.jobe.2024.111402" target="_blank" >10.1016/j.jobe.2024.111402</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Recycling of fly ash and carbide slag in low-carbon cement composites by pre-depolymerization and pre-dissolution treatment

  • Original language description

    The application of high-volume fly ash cement (HVFC) composites is significant for the development of low-carbon building materials, but restricted by poor early and late mechanical properties due to the difficulty in depolymerization of the dense Si-Al network structure on the fly ash (FA) surface without high alkalinity. In this study, aiming to enhance the HVFC performances, a strategy for improving HVFC composites by pre-polymerized FA and pre-dissolved carbide slag waste (CSW) in wet-milling was developed. The mechanochemical process of wet-milling destroyed the Si-Al structure of FA and promoted the leaching of Ca2+ and OH- from CSW, which realizes the pre-polymerization of FA and the pre-dissolution of CSW, producing new phases such as Ca-Al-Cl LDHs and AFt, respectively. The mechanochemical process reduces the reaction threshold between FA and CSW, enabling independent hydration reactions between them. Furthermore, wet milling improves the degree of dissolution of the aluminum phase in FA and OH- in CSW and promotes the Al embedding into the C-S-H gel structure. The early and late compressive strengths of HVFC were greatly improved, with 139 % and 60 % increases in 3 days and 56 days. This work provides feasible strategies to improve the mechanical property limitations of HVFC.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20100 - Civil engineering

Result continuities

  • Project

    <a href="/en/project/EF17_048%2F0007373" target="_blank" >EF17_048/0007373: Damage Prediction of Structural Materials</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2024

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Building Engineering

  • ISSN

    2352-7102

  • e-ISSN

    2352-7102

  • Volume of the periodical

    98

  • Issue of the periodical within the volume

    111402

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    18

  • Pages from-to

    1-18

  • UT code for WoS article

    001368015500001

  • EID of the result in the Scopus database