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Towards Sustainable Proton Exchange Membranes: Materials and Challenges for Water Electrolysis

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27640%2F25%3A10260054" target="_blank" >RIV/61989100:27640/25:10260054 - isvavai.cz</a>

  • Alternative codes found

    RIV/61989100:27650/25:10260054

  • Result on the web

    <a href="https://www.mdpi.com/2073-4441/17/22/3297" target="_blank" >https://www.mdpi.com/2073-4441/17/22/3297</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.3390/w17223297" target="_blank" >10.3390/w17223297</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Towards Sustainable Proton Exchange Membranes: Materials and Challenges for Water Electrolysis

  • Original language description

    This article provides a comparative analysis of sustainable polymer membranes based on biopolymers and Nafion in the context of proton exchange membrane (PEM) for water electrolyzers. Nafion, a perfluorinated polymer, has been a standard choice for PEM applications due to its excellent proton conductivity and chemical stability. However, the sustainability challenges associated with its production, lifecycle and cost necessitate the exploration of alternative materials that may offer comparable performance while being environmentally friendly. The most promising alternative polymer for PEM electrolyzers appears to be cellulose with good thermal stability at 200 degrees C and a water absorption of 35%, which is slightly higher compared to Nafion membranes with a water absorption value of around 30%. Sustainable PEMs also have much lower hydrogen permeability, e.g., chitosan has been determined to have a permeability of 7 barrers, while Nafion is characterized by a value of more than 100 barrers. The biggest drawbacks of sustainable membranes are proton conductivity and durability, where Nafion membranes are still superior. This review also focuses on mechanical properties, chemical resistance, preparation methods and cost-effectiveness. Sustainable polymers show promising properties for supporting efficient hydrogen production, especially in dynamic operating environments facilitated by renewable energy sources.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20500 - Materials engineering

Result continuities

  • Project

    <a href="/en/project/TN02000025" target="_blank" >TN02000025: National Centre for Energy II</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2025

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Water

  • ISSN

    2073-4441

  • e-ISSN

    2073-4441

  • Volume of the periodical

    17

  • Issue of the periodical within the volume

    22

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    44

  • Pages from-to

    nestránkováno

  • UT code for WoS article

    001623522400001

  • EID of the result in the Scopus database

    2-s2.0-105023436413