Liquid phase flow synthesis of butane-1,4-diol over palladium immobilized on the polymeric resin
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27710%2F25%3A10257888" target="_blank" >RIV/61989100:27710/25:10257888 - isvavai.cz</a>
Result on the web
<a href="https://link.springer.com/article/10.1007/s11144-025-02863-7" target="_blank" >https://link.springer.com/article/10.1007/s11144-025-02863-7</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s11144-025-02863-7" target="_blank" >10.1007/s11144-025-02863-7</a>
Alternative languages
Result language
angličtina
Original language name
Liquid phase flow synthesis of butane-1,4-diol over palladium immobilized on the polymeric resin
Original language description
Butane-1,4-diol (BAD) production is estimated to be several million tons per year, and the demand is constantly increasing. On an industrial scale, BAD is produced by the catalytic hydrogenation of 2-butyne-1,4-diol (BYD) at a temperature of (403-433 K) and a pressure range of 1.5 x 107-3 x 107 Pa. However, the reaction at these conditions produces a mixture of difficult products to separate. Therefore, there is still a need to develop an alternative catalyst that is active at mild conditions. Herein, we have revealed the catalytic performance of Pd nanoparticles immobilized on polymeric resin with terminal -NH2 functional groups in the liquid phase flow butane-1,4-diol synthesis under 3 x 105 Pa and 318 K. 2.16 wt% Pd/Polym with an average NP size of 3 nm leads to the formation of 100% butane-1,4-diol while keeping 100% 2-butyne-1,4-diol conversion at mild conditions, exceeding most of the reported results of butane-1,4-diol synthesis.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
20402 - Chemical process engineering
Result continuities
Project
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Continuities
V - Vyzkumna aktivita podporovana z jinych verejnych zdroju
Others
Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Reaction kinetics, mechanisms and catalysis
ISSN
1878-5190
e-ISSN
1878-5204
Volume of the periodical
Neuveden
Issue of the periodical within the volume
May
Country of publishing house
US - UNITED STATES
Number of pages
13
Pages from-to
2247-2259
UT code for WoS article
001492129600001
EID of the result in the Scopus database
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