X-RAY STRUCTURE OF [Cu(dimeen)(ox)(H2O)]2[Cu(dimeen)2](ClO4)2.

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F01%3A00001312" target="_blank" >RIV/61989592:15310/01:00001312 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/01:00001528
Result on the web
—
DOI - Digital Object Identifier
—

Result language
angličtina
Original language name
X-RAY STRUCTURE OF [Cu(dimeen)(ox)(H2O)]2[Cu(dimeen)2](ClO4)2.
Original language description
The crystal and molecular structure of the title complex compound (dimeen = N,N-dimethylethylenediamine, ox = oxalate) has been solved by heavy atom methods and basic physico-chemical measurements have been made. It was found that the structure containstwo non-equivalent copper atoms in the slightly distorted square-planar for Cu(2) and square-pyramidal for Cu(1) coordination with deviations of atom positions from ideal Cu(1)N(1)N(2)O(3)O(4) plane smaller then 0.28 A.The results of magnetochemical measurements (#eff = 1.82 BM/294 K) correspond with assumption of copper in the oxidation state II. The value of molar conductivity in water (c = 10-3 mol/l, lM = 307 Scm2mol-1) confirms the 1:2 electrolyte with ClO4- group out from the coordination sphere of both central atoms; the characteristic absorption for this group at 1068 cm-1 and 620 cm-1 were also found in the IR-spectrum.
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—

Publication year
2001
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical
Materials structure in Chemistry, Biology, Physics and Technology
ISSN
1211-5894
e-ISSN
—
Volume of the periodical
8
Issue of the periodical within the volume
1a
Country of publishing house
CZ - CZECH REPUBLIC
Number of pages
2
Pages from-to
62-63
UT code for WoS article
—
EID of the result in the Scopus database
—

Similar results(10)