NICKEL(II)DITHIOCARBAMATESWITH POLYDENTATE P-LIGANDSIN THE COORDINATION SPHERE

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F02%3A00001601" target="_blank" >RIV/61989592:15310/02:00001601 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
NICKEL(II)DITHIOCARBAMATESWITH POLYDENTATE P-LIGANDSIN THE COORDINATION SPHERE
Original language description
The diamagnetic nickel(II) dithiocarbamates with tridentate P,P,P-ligands of composition [Ni(bziprdtc)(triphosI)]X (bziprdtc = benzylisopropyldithiocarbamate, triphosI= C34H33P3 = bis(2-diphenylphosphinoethyl)phenylphosphine,X = Cl-, PF6-,BPh4-, ClO4-; Ph = phenyl), [Ni(tzdtc)(triphosI)]X (tzdtc = thiazolidinedithiocarbamate, X = Cl-, PF6-), [Ni(hmidtc)(triphosI)]X (hmidtc = hexamethyleneiminedithiocarbamate, Cl-, PF6-) and [Ni(hmidtc)(triphosII)]X (triphosII = C41H39P3 = 1,1,1-tris(diphenylphosphinomethyl)ethan, X = Cl-, PF6-) have been isolated. The compounds were studied by thermal analysis, IR and UV-VIS spectroscopy, magnetochemical and conductivity measurements. All compounds are diamagnetic, 1 : 1 electrolytes, with coordination number five ofnickel in the NiS2P3 chromophore.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Publication year
2002
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical
Acta Universitatis Palackianae Olomucensis, Facultas Rerum Naturalium, Chemica
ISSN
0232-0061
e-ISSN
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Volume of the periodical
41
Issue of the periodical within the volume
N
Country of publishing house
CZ - CZECH REPUBLIC
Number of pages
5
Pages from-to
37-41
UT code for WoS article
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EID of the result in the Scopus database
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