Nickel(II) dithiocarbamates with bis(2-diphenylphosphinoethyl)phenylphosphine

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F04%3A00002227" target="_blank" >RIV/61989592:15310/04:00002227 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/04:00009889
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Nickel(II) dithiocarbamates with bis(2-diphenylphosphinoethyl)phenylphosphine
Original language description
A Ni(II) dithiocarbamates with the tridentate P,P,P-ligand of composition [Ni(pe2dtc)(triphosI)]X (triphos = C34H33P3 = bis(2-diphenylphosphinoethyl)phenylphosphine, pe2dtc = dipentyldithiocarbamate, X = Cl, PF6, ClO4), [Ni(bz2dtc)(triphosI)]X (bz2dtc =dibenzyldithiocarbamate, X = Cl, PF6, Bph, ClO4) have been synthesized and studied by thermal analysis, IR and UV/VIS spectroscopy, P31{H1} NMR spectroscopy, magnetochemical and conductivity measurements. All complexes are diamagnetic, 1:1 electrolytes.X-ray structural analysis was solved for the [Ni(pe2dtc)(triphosI)]PF6 and [Ni(bz2dtc)(triphosI)]PF6; the presence of NiS2P3 chromophore with penta-coordianted central atom was confirmed.
Czech name
Nikelnaté dithiokarbamáty s bis(2-difenylfosfinoethyl)fenylfosfinem
Czech description
Byly syntetizovány a termickou analýzou studovány nové nikelnaté dithiokarbamáty s bis(2-difenylfosfinoethyl)fenylfosfinem.

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Publication year
2004
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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