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Nickel(II) dithiocarbamates with bis(2-diphenylphosphinoethyl)phenylphosphine

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F04%3A00002227" target="_blank" >RIV/61989592:15310/04:00002227 - isvavai.cz</a>

  • Alternative codes found

    RIV/61989592:15310/04:00009889

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Nickel(II) dithiocarbamates with bis(2-diphenylphosphinoethyl)phenylphosphine

  • Original language description

    A Ni(II) dithiocarbamates with the tridentate P,P,P-ligand of composition [Ni(pe2dtc)(triphosI)]X (triphos = C34H33P3 = bis(2-diphenylphosphinoethyl)phenylphosphine, pe2dtc = dipentyldithiocarbamate, X = Cl, PF6, ClO4), [Ni(bz2dtc)(triphosI)]X (bz2dtc =dibenzyldithiocarbamate, X = Cl, PF6, Bph, ClO4) have been synthesized and studied by thermal analysis, IR and UV/VIS spectroscopy, P31{H1} NMR spectroscopy, magnetochemical and conductivity measurements. All complexes are diamagnetic, 1:1 electrolytes.X-ray structural analysis was solved for the [Ni(pe2dtc)(triphosI)]PF6 and [Ni(bz2dtc)(triphosI)]PF6; the presence of NiS2P3 chromophore with penta-coordianted central atom was confirmed.

  • Czech name

    Nikelnaté dithiokarbamáty s bis(2-difenylfosfinoethyl)fenylfosfinem

  • Czech description

    Byly syntetizovány a termickou analýzou studovány nové nikelnaté dithiokarbamáty s bis(2-difenylfosfinoethyl)fenylfosfinem.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2004

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Polish Journal of Chemistry

  • ISSN

    0137-5083

  • e-ISSN

  • Volume of the periodical

    78

  • Issue of the periodical within the volume

    5

  • Country of publishing house

    PL - POLAND

  • Number of pages

    11

  • Pages from-to

    623-633

  • UT code for WoS article

  • EID of the result in the Scopus database