Nickel(II) Dithiocarbamates with AsI3 and SbI3 as Mixed Ligands

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F05%3A00001857" target="_blank" >RIV/61989592:15310/05:00001857 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Nickel(II) Dithiocarbamates with AsI3 and SbI3 as Mixed Ligands
Original language description
Ni(II) dithiocarbamates with AsI3 and SbI3 as ligands of the composition [Ni(hmidtc)2(AsI3)] (1), [Ni(bzbutdtc)2(AsI3)] (2), [Ni(bzbutdtc)2(SbI3)].2CHCl3 (3), [Ni(bz2dtc)2(AsI3)] (4), [Ni(bz2dtc)(SbI3)].CS2 (5), [Ni(bz2dtc)2(AsI3)2].CHCl3 (6), [Ni(hmidtc)2(SbI3)2] (7) and [Ni(cetdtc)2(AsI3)2] (8), (hmidtc = hexamethyleneiminedithiocarbamate, bzbutdtc = benzylbutyldithiocarbamate, bz2dtc = dibenzyldithiocarbamate, cetdtc = cyclohexylethyldithiocarbamate, dtc = S2CN-) have been synthesized. The complexeshave been characterized by elemental analysis, thermal analysis, IR and UV/VIS spectroscopies, magnetochemical and conductivity measurements as square-pyramidal (1-5) and octahedral (6-8) complexes. X-ray analysis of [Ni(bz2dtc)2(AsI3)] and [Ni(bz2dtc)2(SbI3)].CS2 confirmed square-pyramidal arrangement around nickel in both complexes with the NiS4As and NiS4Sb chromophore, respectively.
Czech name
Nikelnaté dithikarbamáty s AsI3 a SbI3 jako směsnými ligandy
Czech description
Nikelnaté dithikarbamáty s AsI3 a SbI3 jako směsnými ligandy byly charakterizovány elementární, termickou, rentgenovou, spektroskopickou, magnetochemickou a konduktometrickou analýzou.

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA203%2F02%2F0436" target="_blank" >GA203/02/0436: Application of Crystallographic Databases in Scientific Practice</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2005
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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