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Tetracyanonickelates(II) of copper(II) with Bidentate, Tridentate, and Tetradentate N-Donor Ligands

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F05%3A00002248" target="_blank" >RIV/61989592:15310/05:00002248 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Tetracyanonickelates(II) of copper(II) with Bidentate, Tridentate, and Tetradentate N-Donor Ligands

  • Original language description

    The following complexes, having the general formula [Cu(L)2Ni(CN)4] . xH2O (L = N-methylethylenediamine (x = 0) or 1,3-diaminopentane (x = 0)) and [Cu(L)Ni(CN)4] . xH2O (L = 3-(methylamino)propylamine (x = 0), 3-(dimethylamino)propylamine (x = 1), N,N'-dibenzylethylenediamine (x = 2), 2,6-di(2-pyridyl)pyridine (x = 2), N,N'-bis(3-aminopropyl)ethylenediamine (x = 1), 1,3,6,10,12,15-hexaazatricyclo[13.3.1.1(6.10)]eicosane (x = 0)) 1,3,6,11,14-hexaazatricyclo[12.2.1.1(6.9)]octadecane]h (x = 0) or 1,8-dimethyl-1,3,6,10,13-hexaaazacyclotetradecane (x = 0)) have been synthesized. All the compounds have been characterized by elemental analyses, IR and UV-VIS spectroscopies and magnetic measurements. The complex [Cu(1,3-diaminopentane)2Ni(CN)4] . xH2O was studied using thermal analysis (the product of the thermal decomposition of this compound is the mixture of CuO and NiO as determined by X-ray powdre diffraction). The structure of the studied complexeswith cyanide bridges between square-plan

  • Czech name

    Tetrakyanonikelnatany měďnaté s bidentátními, tridentátními a tetradentátními N-donorovými ligandy

  • Czech description

    Byly studovány tetrakyanonikelnatany měďnaté s bidentátními, tridentátními a tetradentátními N-donorovými ligandy.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2005

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Chemical Papers

  • ISSN

    0366-6352

  • e-ISSN

  • Volume of the periodical

    59

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    4

  • Pages from-to

    89-92

  • UT code for WoS article

  • EID of the result in the Scopus database