Tetracyanopalladnates(II) and tetracyanoplatinates(II) of copper(II) with triamines or tetramines as chelating ligands
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F06%3A00002648" target="_blank" >RIV/61989592:15310/06:00002648 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Tetracyanopalladnates(II) and tetracyanoplatinates(II) of copper(II) with triamines or tetramines as chelating ligands
Original language description
Eight new complexes of composition [Cu(L)Pd(CN)4].xH2O and [Cu(L)Pt(CN)4] (L = 1,4-bis(3-aminopropyl)piperazine); N,N´-bis(3-aminopropyl)-1,2-diaminoethane, dipropylenetriamine, N-(2-aminoethyl)-1,3-diaminopropane) have been prepared by the reactions ofK2[M(CN)4] (M=Pd, Pt) with the complex [Cu(L)](ClO4)2 or Cu(ClO4)2.6H2O and appropriate amine in water and characterized by IR and magnetic measurements. The temperature dependence of magnetic susceptibility was measured for complex [Cu(L)Pd(CN)4].H2O (L= N,N´-bis(3-aminopropyl)-1,2-diaminoethane) but exchange interaction between copper(II) atoms was not found.
Czech name
Tetrakyanopalladnatany a tetrakyanoplatnatany měďnaté s triaminy a tetraminy jako chelatotvornými ligandy
Czech description
Osm nových komplexů o složení [Cu(L)Pd(CN)4].xH2O a [Cu(L)Pt(CN)4] (L = 1,4-bis(3-aminopropyl)piperazin); N,N´-bis(3-aminopropyl)-1,2-diaminoethan, dipropylentriamin, N-(2-aminoethyl)-1,3-diaminopropan) byly připraveny reakcí K2[M(CN)4] (M=Pd, Pt) s komplexem [Cu(L)](ClO4)2 nebo Cu(ClO4)2.6H2O a vhodným aminem ve vodě a charakterizovány pomocí IR spekter a magnetického měření. Teplotní závislost magnetické susceptibility byla změřena u komplexu [Cu(L)Pd(CN)4].H2O (L = N,N´-bis(3-aminopropyl)-1,2-diaminoethan) ale výměnná interakce mezi atomy mědi(II) nebyla nalezena.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F98%2FP221" target="_blank" >GA203/98/P221: Polynuclear complexes of elements of iron triad and cooper with cyanide bridges - their structure and magnetic properties</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2006
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Acta Universitatis Palackianae Olomucensis, Facultas Rerum Naturalium, Chemica
ISSN
0232-0061
e-ISSN
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Volume of the periodical
45
Issue of the periodical within the volume
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Country of publishing house
CZ - CZECH REPUBLIC
Number of pages
9
Pages from-to
43-51
UT code for WoS article
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EID of the result in the Scopus database
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