Low-dimensional compounds containing cyanido groups. XXIV. Crystal structure, spectroscopic and thermal properties of two Cu(II) tetracyanidoplatinate complexes with tetradentate N-donor ligands

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F14%3A00422560" target="_blank" >RIV/68378271:_____/14:00422560 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.ica.2013.09.016" target="_blank" >http://dx.doi.org/10.1016/j.ica.2013.09.016</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ica.2013.09.016" target="_blank" >10.1016/j.ica.2013.09.016</a>

Result language
angličtina
Original language name
Low-dimensional compounds containing cyanido groups. XXIV. Crystal structure, spectroscopic and thermal properties of two Cu(II) tetracyanidoplatinate complexes with tetradentate N-donor ligands
Original language description
Violet crystals of [Cu2(teta)2Pt(CN)4]2[Pt(CN)4]2 (1, teta = N,N?-bis(2-aminoethyl)-1,2-diaminoethane; tri- ethylenetetramine) and {[Cu3(bapen)3Pt(CN)4][Pt(CN)4]213H2O}n (2, bapen = N,N? -bis(3-aminopropyl)- 1,2-diaminoethane) were characterized using elemental analysis, IR and UV?Vis spectroscopy, thermal and X-ray crystal structure analysis. Two m(C?N) absorption bands in the IR spectra of the complexes imply non-equivalency of cyanido groups. X-ray crystal structure analysis has shown that complex 1is of ionic character and is formed from a couple of trinuclear [Cu(teta)-Pt(CN)4- Cu(teta)]2+ complex cations and a couple of discrete [Pt(CN)4]2- anions. On the other hand, complex 2 is of polymeric character.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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