Syntheses and study on nickel nad copper complexes with 1,3,5-benzenetricarboxylic acid. Crystal and molecular structure of [Cu3(mdpta)3(btc)](ClO4)3.4H2O

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F07%3A00009829" target="_blank" >RIV/61989592:15310/07:00009829 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Syntheses and study on nickel nad copper complexes with 1,3,5-benzenetricarboxylic acid. Crystal and molecular structure of [Cu3(mdpta)3(btc)](ClO4)3.4H2O

Original language description

Nickel and copper complexes containing 1,3,5-benzenetricarboxylic acid, with a combination of selected N-donor ligands and Schiff bases, of the composition Ni3(bimz)6(btc)2.12H2O (1), Ni3(btz)9(btc)2.12H2O (2), Ni2(L1)(btc).7H2O (3), Ni3(L2)2(Hbtc).9H2O(4), Ni2(L3)(btc).4H2O (5), Cu2(L4)(tc).7H2O (6), [Cu3(pmdien)3(btc)](ClO4)3.6H2O (7) and [Cu3(mdpta)3(btc)](ClO4)3.4H2O (8); H3btc = 1,3,5-benzenetricarboxylic acid, bimz = benzimidazole, btz = benztriazole, L1 = 2-[(phenylimino)methyl]phenol, L2 = N,N'-bis(salicylidene)propylenediamine, L3 = 2-[(2-nitrophenyl)methylene]phenol, L4 = 2-[(4-methoxy-phenylimino)methyl]phenol, pmdien = N,N,N',N'', N''-pentamethyldiethylenetriamine, mdpta = N,N-bis(3-aminopropyl)methylamine, have been synthesized. The crystal and molecular structure of complex 8 was solved. The complex is trinuclear with btc3- bridge.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

S - Specificky vyzkum na vysokych skolach

Publication year

2007

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Polyhedron

ISSN

0277-5387

e-ISSN

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Volume of the periodical

26

Issue of the periodical within the volume

3

Country of publishing house

GB - UNITED KINGDOM

Number of pages

8

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

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