Synthesis, characterization and in vitro cytotoxicity of the first palladium(II) oxalato complexes involving adenine based ligands

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F09%3A00010068" target="_blank" >RIV/61989592:15310/09:00010068 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Synthesis, characterization and in vitro cytotoxicity of the first palladium(II) oxalato complexes involving adenine based ligands

Original language description

The first [Pd(Ln)2(ox)] . xH2O oxalato (ox) complexes involving 2 chloro-N6-(benzyl)-9-isopropyladenine (L1; complex 1), 2 chloro-N6-(4-methoxybenzyl)-9-isopropyladenine (L2; 2), 2 chloro-N6-(2,3-dimethoxybenzyl)-9-isopropyladenine (L3; 3), 2 chloro-N6-(2,4-dimethoxybenzyl)-9-isopropyladenine (L4; 4), and 2 chloro-N6-(4-methylbenzyl)-9-isopropyladenine (L5; 5) have been synthesized by the reactions of potassium bis(oxalato)palladate(II) dihydrate, [K2Pd(ox)2].2H2O, with the mentioned organic compounds (H2ox = oxalic acid; x = 0 for 1-3 and 5 or 2 for 4). Elemental analyses (C, H, N), FTIR, Raman and NMR (1H, 13C, 15N) spectroscopies, conductivity measurements and thermal studies (thermogravimetric and differential thermal analysis, TG/DTA) have been used to characterize the prepared complexes. The molecular structures of [Pd(L2)2(ox)] (2) and [Pd(L5)2(ox)] . L5 . Me2CO (5 . L5 . Me2CO) have been determined by a single crystal X ray analysis. The geometry of these complexes is slightly

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Inorganic Biochemistry

ISSN

0162-0134

e-ISSN

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Volume of the periodical

103

Issue of the periodical within the volume

7

Country of publishing house

US - UNITED STATES

Number of pages

11

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

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