Experimental and Computational Study of the Structural and Electronic Properties of FeII(2,2-bipyridine)(mes)2 and [FeII(2,2-bipyridine)(mes)2]-, a Complex Containing a 2,2-Bipyridyl Radical Anion
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F10%3A10213080" target="_blank" >RIV/61989592:15310/10:10213080 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Experimental and Computational Study of the Structural and Electronic Properties of FeII(2,2-bipyridine)(mes)2 and [FeII(2,2-bipyridine)(mes)2]-, a Complex Containing a 2,2-Bipyridyl Radical Anion
Original language description
Addition of potassium metal and 2,2,2-crypt (4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) to a tetrahydrofuran (THF) solution of Fe(2,20-bipyridine)(mes)2 (1; mes = 2,4,6-Me3C6H2) yielded the anionic komplex [Fe(2,2-bipyridine)(mes)2]- which was isolated as [K(2,2,2-crypt)][Fe(2,2-bipyridine)(mes)2] (2) alongside the side-product [K(2,2,2-crypt)][Fe(mes)3] 3 C6H12 (3). A compositionally pure sample of 2 was obtained by dissolving a mixture of 2 and 3 in dry pyridine and layering the resulting solution with toluene. Solid state magnetic susceptibility measurements on 1 reveal Curie-Weiss paramagnetic behavior with a molar magnetic moment of 5.12(1) mýB between 20 and 300 K, a value which is in line with the expected iron(II) spin-only value of 4.90 mýB.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorganic Chemistry
ISSN
0020-1669
e-ISSN
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Volume of the periodical
49
Issue of the periodical within the volume
13
Country of publishing house
US - UNITED STATES
Number of pages
12
Pages from-to
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UT code for WoS article
000279211500046
EID of the result in the Scopus database
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