A Homologous Series of First-Row Transition-Metal Complexes of 2,2 '-Bipyridine and their Ligand Radical Derivatives: Trends in Structure, Magnetism, and Bonding

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F12%3A33140847" target="_blank" >RIV/61989592:15310/12:33140847 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/ic301587f" target="_blank" >http://dx.doi.org/10.1021/ic301587f</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/ic301587f" target="_blank" >10.1021/ic301587f</a>

Result language
angličtina
Original language name
A Homologous Series of First-Row Transition-Metal Complexes of 2,2 '-Bipyridine and their Ligand Radical Derivatives: Trends in Structure, Magnetism, and Bonding
Original language description
The organometallic first-row transition-metal complexes [M(2,2'-bipy)(mes)(2)] (M = Cr (1), Mn (2), Co (4), Ni (5); 2,2'-bipy = 2,2'-bipyridine; mes = 2,4,6-Me3C6H2) were reacted with potassium and a suitable alkali-metal sequestering agent to yield salts of the anionic species [M(2,2'-bipy)(mes)(2)](-). The neutral parent compounds and their corresponding anionic congeners were characterized by single-crystal X-ray diffraction in [Cr(2,2'-bipy)(mes)(2)].1.5C(6)H(6), [Mn(2,2'-bipy)(mes)(2)], [Co(2,2'-bipy)(mes)(2)].THF, [Ni(2,2'-bipy)(mes)(2)], [K(dibenzo-18-crown-6).THF][Cr(2,2'-bipy)(mes)(2)].2THF, [K(18-crown-6)][Mn(2,2'-bipy)(mes)(2)].2THF, [K(18-crown-6)] [Mn(2,2'-bipy)(mes)(2)].0.67py.0.67tol, [K(2,2,2-crypt)] [Co(2,2'-bipy)(mes)(2)], and [K(2,2,2-crypt)][Ni(2,2'-bipy)(mes)(2)]. These species, along with the previously reported neutral iron complexes [Fe(2,2'-bipy)(mes)(2)](0/-) (3/3(-)), form a homologous series of compounds which allow for an in-depth study of the interactions
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/ED2.1.00%2F03.0058" target="_blank" >ED2.1.00/03.0058: Regional Centre of Advanced Technologies and Materials</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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