Synthesis, spectral (UV-Vis,IR,ESI-MS), magnetic and structural characterizations and the antimicrobial effect of potassium isothiocyanato-(N-salicylidene-aminoand the antimicrobial effect of potassium isothiocyanato-(N-salicylidene-aminoacidato)cuprates

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F10%3A10213084" target="_blank" >RIV/61989592:15310/10:10213084 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Synthesis, spectral (UV-Vis,IR,ESI-MS), magnetic and structural characterizations and the antimicrobial effect of potassium isothiocyanato-(N-salicylidene-aminoand the antimicrobial effect of potassium isothiocyanato-(N-salicylidene-aminoacidato)cuprates

Original language description

A series of potassium isothiocyanato-(N-salicylidene-amino acidato)cuprates with the general formulas of K2[Cu2(sal-aa)2(l-NCS)2]nH2O, where n = 0 or 4 and (sal-aa) stands for the dianion of N-salicylideneamino acid derived from glycine (I), DL-a-alanine(II), DL-valine (III), DL-phenylalanine (IV), and {K[Cu(sal-bala)(l-NCS)]}n for b-alanine (V), respectively, was synthesized and fully characterized by elemental analysis, UV-Vis and IR spectroscopy, ESI-MS spectrometry, magnetic measurements, and X-raystructural analysis (II and IV). It has been found that the copper(II) atom adopts a distorted square-pyramidal surrounding in the dimeric complexes I-IV, while the geometry in the polymeric complex V can be described as distorted square-bipyramidal. The analysis of magnetic properties revealed weak antiferromagnetic exchanges in the dinuclear species I-IV and an alternating ferro/antiferromagnetic exchange in the case of 1D-polymeric compound V.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2010

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Inorganica Chimica Acta

ISSN

0020-1693

e-ISSN

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Volume of the periodical

363

Issue of the periodical within the volume

14

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

10

Pages from-to

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UT code for WoS article

000283051600035

EID of the result in the Scopus database

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