catena-Poly[potassium [copper(II)-mu-isothiocyanato-mu-N-salicylidene-beta-alaninato(2-)]]

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14330%2F03%3A00009082" target="_blank" >RIV/00216224:14330/03:00009082 - isvavai.cz</a>

Alternative codes found

RIV/00216224:14330/03:00008597 RIV/62157124:16370/03:00000014

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

catena-Poly[potassium [copper(II)-mu-isothiocyanato-mu-N-salicylidene-beta-alaninato(2-)]]

Original language description

The title polymeric compound, catena-poly[dipotassium [bis[mu-N-salicylidene-beta-alaninato(2-)]-kappa4 O,N,O':O'';kappa4 O'':O,N,O'-dicopper(II)]-di-mu-isothiocyanato-kappa2 N:S;kappa2 S:N], {K[Cu(NCS)(C10H9NO3)]}n, consists of [isothiocyanato(N-salicylidene-beta-alaninato)copper(II)]- anions connected through the two three-atom thiocyanate (mu-NCS) and the two anti,anti-mu-carboxylate bridges into infinite one-dimensional polymeric anions, with coulombically interacting K+ counter-ions with coordination number 7 constrained between the chains. The CuII atoms adopt a distorted tetragonal-bipyramidal coordination, with three donor atoms of the tridentate Schiff base and one N atom of the bridging mu-NCS ligand in the basal plane. The first axial position is occupied by a thiocyanate S atom of a symmetry-related mu-NCS ligand at an apical distance of 2.9770 (8) A, and the second position is occupied by an O atom of a bridging carboxylate group from an adjacent coordination unit at a dis

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

<a href="/en/project/GA203%2F02%2F0436" target="_blank" >GA203/02/0436: Application of Crystallographic Databases in Scientific Practice</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2003

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Acta Crystallographica Section C: Crystal Structure

ISSN

0108-2701

e-ISSN

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Volume of the periodical

2003

Issue of the periodical within the volume

12

Country of publishing house

GB - UNITED KINGDOM

Number of pages

3

Pages from-to

"m509"-"m511"

UT code for WoS article

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EID of the result in the Scopus database

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