Di-mu-aqua-bis[(N-salicylidene-beta-alaninato-kappa3 O,N,O')copper(II)] urea disolvate

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F04%3A00010076" target="_blank" >RIV/00216224:14310/04:00010076 - isvavai.cz</a>
Alternative codes found
RIV/62157124:16370/04:00000087
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Di-mu-aqua-bis[(N-salicylidene-beta-alaninato-kappa3 O,N,O')copper(II)] urea disolvate
Original language description
Crystals of the title compound, [Cu2(C10H9NO3)2(H2O)2].2CH4N2O, consist of two (N-salicylidene-beta-alaninato-kappa3 O,N,O')copper(II) coordination units bridged by two water moieties to form a dimer residing on a crystallographic inversion center, alongwith two uncoordinated urea molecules. The CuII atom has square-pyramidal coordination, with three donor atoms of the tridentate Schiff base and an O atom of the bridging aqua ligand in the basal plane. The axial position is occupied by the second bridging water ligand at a distance of 2.5941 (18) A. Hydrogen bonds between molecules of urea and the neighboring dimer units lead to the formation of a two-dimensional grid of molecules parallel to [101]. The superposition of the normals of the pyramidal base planes in the direction [100] indicates possible pi-pi interactions between the neighboring units.
Czech name
Di-mu-aqua-bis[(N-salicylidene-beta-alaninato-kappa3 O,N,O')měďnatý] komplex s močovinou
Czech description
V práci je popisována RTG struktura titulního měďnatého komplexu.

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA203%2F02%2F0436" target="_blank" >GA203/02/0436: Application of Crystallographic Databases in Scientific Practice</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2004
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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