([mu]-5-Carboxybenzene-1,3-dicarboxylato-[kappa]2O1:O3)bis[bis(2,2'-bipyridine-[kappa]2N,N')copper(II)] 5-carboxybenzene-1,3-dicarboxylate 2,2'-bipyridine solvate tridecahydrate

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F08%3A00005559" target="_blank" >RIV/61989592:15310/08:00005559 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

([mu]-5-Carboxybenzene-1,3-dicarboxylato-[kappa]2O1:O3)bis[bis(2,2'-bipyridine-[kappa]2N,N')copper(II)] 5-carboxybenzene-1,3-dicarboxylate 2,2'-bipyridine solvate tridecahydrate

Original language description

The asymmetric unit of the title complex, [Cu2(C9H4O6)(C10H8N2)4](C9H4O6).C10H8N2.13H2O, comprises two formula units. The two CuII centres are bridged by a 5-carboxybenzene-1,3-dicarboxylate (Hbtc) ligand. Each of the metal centres is bonded to four N atoms of two bidentate 2,2'-bipyridine ligands (bpy) and one O atom of the Hbtc ligand in a highly distorted square-pyramidal geometry. The secondary structure is stabilized by a variety of O-H...O hydrogen bonds and [pi]-[pi] stacking interactions connecting the complex cations, Hbtc anions, bpy and water molecules of crystallization. Three water molecules are disordered over two positions, with site occupancy factors of ca 0.8 and 0.2.

Czech name

([mu]-5-Karboxybenzen-1,3-dikarboxylato-[kappa]2O1:O3)bis[bis(2,2'-bipyridin-[kappa]2N,N')měď(II)] 5-karboxybenzen-1,3-dikarboxylate 2,2'-bipyridin solvát tridekahydrát

Czech description

Byla vyřešena molekulová struktura komplexu o složení [Cu2(C9H4O6)(C10H8N2)4](C9H4O6).C10H8N2.13H2O, kde atomy mědi jsou spojeny 5-karboxybenzen-1,3-dikarboxylato (Hbtc) můstkovým ligandem. Navíc je každý atom mědi koordinován dvěma 2,2'-bipyridin ligandy.

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2008

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Acta Crystallographica Section E - Structure Reports Online

ISSN

1600-5368

e-ISSN

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Volume of the periodical

64

Issue of the periodical within the volume

2

Country of publishing house

DK - DENMARK

Number of pages

1

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

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