Disruption of "Coordination Polymer" Architecture in Cu2+ Bis-Phosphonates and Carboxyphosphonates by Use of 2,2 '-Bipyridine as Auxiliary Ligand: Structural Variability and Topological Analysis

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F13%3A10189987" target="_blank" >RIV/00216208:11310/13:10189987 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1021/cg4009625" target="_blank" >http://dx.doi.org/10.1021/cg4009625</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/cg4009625" target="_blank" >10.1021/cg4009625</a>

Result language

angličtina

Original language name

Disruption of "Coordination Polymer" Architecture in Cu2+ Bis-Phosphonates and Carboxyphosphonates by Use of 2,2 '-Bipyridine as Auxiliary Ligand: Structural Variability and Topological Analysis

Original language description

The outcome of a synthesis involving a metal ion and a (poly)phosphonic acid depends on a plethora of variables such as solution pH, reactant molar ratios, nature of the metal ion, number of phosphonate groups, and other "functional" moieties present onthe ligand backbone. Products are usually coordination polymers of diverse dimensionality. Here we report that the use of a chelating auxiliary ligand (2,2'-bpy) can "disrupt" the polymeric architecture of the copper phosphonate, causing the isolation ofa series of molecular complexes (mononuclear or binuclear) that incorporate both the phosphonate and the 2,2'-bpy ligands. Synthetic details, crystal structures, and intermolecular interactions (pi-pi stacking and hydrogen bonding) are discussed. The structures of the obtained Cu complexes are extended into 2D or 3D networks via multiple hydrogen bonds involving the molecular units and crystallization water molecules. These H-bonded networks have been classified from the topological vie

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2013

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Crystal Growth and Design

ISSN

1528-7483

e-ISSN

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Volume of the periodical

13

Issue of the periodical within the volume

10

Country of publishing house

IN - INDIA

Number of pages

10

Pages from-to

4480-4489

UT code for WoS article

000326300200046

EID of the result in the Scopus database

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