Synthesis, crystal structure and magnetic properties of novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN)-Cu(ept)](n)center dot 4nH(2)O (ept = N-(2-aminoethyl)propane-1,3-diamine)
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F01%3A00001648" target="_blank" >RIV/61989592:15310/01:00001648 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Synthesis, crystal structure and magnetic properties of novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN)-Cu(ept)](n)center dot 4nH(2)O (ept = N-(2-aminoethyl)propane-1,3-diamine)
Original language description
The novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN) Cu(ept)](n)(.)4nH(2)O (ept = N-(2-aminoethyl)-propane-1,3 diamine) was obtained by the reaction of Cu(ClO4)(2)(.)6H(2)O with N-(2-aminoethyl)propane-1,3-diamine and Na 2[Fe(CN)(5)NO](.)2H(2)O in water. This compound was characterized by IR, UV-VIS and EPR spectroscopies and magnetic measurement. Single-crystal X-ray structure analysis revealed that the title complex has a one-dimensional polymeric structure containing hexacoordinate iron(II) with five cyanide ligands (two of them, in trans position, bridging) and one nitrosyl group, and pentacoordinate copper(II) with N-(2 aminoethyl)propane-1,3-diamine and two sites occupied by bridging cyanide ligands. Magnetic investigation revealed a very weak anti ferromagnetic interaction between the copper atoms (superexchange interaction parameter J = -1.7(1) cm(-1); H = -JS(i)S(i+1)) within the chain through the diamagnetic [Fe(CN)(5)NO](2-) ions.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2001
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Collection of Czechoslovak Chemical Communications
ISSN
0010-0765
e-ISSN
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Volume of the periodical
66
Issue of the periodical within the volume
10
Country of publishing house
CZ - CZECH REPUBLIC
Number of pages
9
Pages from-to
1490-1498
UT code for WoS article
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EID of the result in the Scopus database
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