Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4]
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F11%3A33116864" target="_blank" >RIV/61989592:15310/11:33116864 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.poly.2011.08.022" target="_blank" >http://dx.doi.org/10.1016/j.poly.2011.08.022</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2011.08.022" target="_blank" >10.1016/j.poly.2011.08.022</a>
Alternative languages
Result language
angličtina
Original language name
Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4]
Original language description
Fourteen octahedral Ni(IV) dithiocarbamato complexes of the general formula [Ni(ndtc)3]X.yH2O {ndtc stands for the appropriate dithiocarbamate anion, X stands for ClO4- (1-8; y = 0) or [FeCl4]- (9-14; y = 0 for 9-12, 1 for 13 and 0.5 for 14) was preparedby the oxidation of the corresponding Ni(II) complexes, i.e. [Ni(ndtc)2], with NOClO4 or FeCl3. The complexes, involving a high-valent Ni(IV)S6 core, were characterized by elemental analysis (C, H, N. Cl and Ni), UV-Vis and FTIR spectroscopy, thermal analysis and magnetochemical and conductivity measurements. The X-ray structure of {Ni(hmidtc)3][FeCl4] (9) was determined and this revealed slightly distorted octahedral and tetrahedral geometries within the complex cations, and anions, respectively. Moreover, the formal oxidation state of iron in (FeCl4]- as well as the coordination geometry in its vicinity was also proved by 57Fe Mossbauer spectroscopy in the case of 9.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Polyhedron
ISSN
0277-5387
e-ISSN
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Volume of the periodical
30
Issue of the periodical within the volume
17
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
2795-2800
UT code for WoS article
000296996500006
EID of the result in the Scopus database
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