Synthesis and X-ray structure of nickel(II) benzylpiperazine-dithiocarbamate complex [Ni(bpdtc)(PPh3)2]ClO4PPh3

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F13%3A33146056" target="_blank" >RIV/61989592:15310/13:33146056 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.molstruc.2013.06.021" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2013.06.021</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2013.06.021" target="_blank" >10.1016/j.molstruc.2013.06.021</a>

Result language
angličtina
Original language name
Synthesis and X-ray structure of nickel(II) benzylpiperazine-dithiocarbamate complex [Ni(bpdtc)(PPh3)2]ClO4PPh3
Original language description
A mixed-ligand nickel(II) dithiocarbamate complex of the composition [Ni(bpdtc)(PPh3)2]ClO4PPh3 was synthesized, characterized (elemental analysis, UV-Vis, IR and NMR spectroscopy and molar conductivity measurements) and its X-ray structure was determined. The three ligands are arranged in a distorted square-planar geometry (an S2P2 donor set), with the bond lengths and angles within the vicinity of the central atom as follows: Ni-P = 2.2150(6) and 2.2529(6) ?, Ni-S = 2.2267(6) and 2.2129(6) ?, P-Ni-P =105.11(2), S-Ni-S = 78.26(2). The P-Ni-P angle of the studied complex falls outside the interval of 98.37-102.92 determined for thirteen formerly reported structural analogues involving the [Ni(ndtc)(PPh3)2]+ moiety with a combination of dithiocarbamate(ndtc) and triphenylphosphine (PPh3) ligands. In the crystal, the complex cations, perchlorate anions and PPh3 molecules of crystallization are linked through intramolecular C-H...O and C-H...pi and intermolecular C-H...O, C-H...C and C-
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)