Cisplatin and oxaliplatin derivatives involving 7-azaindole: Structural characterisations

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F12%3A33140839" target="_blank" >RIV/61989592:15310/12:33140839 - isvavai.cz</a>
Result on the web
<a href="http://ac.els-cdn.com/S0277538711007510/1-s2.0-S0277538711007510-main.pdf?_tid=f290745e-7b5e-11e2-813b-00000aacb361&acdnat=1361366030_ee722d46031401e078f413732a8289f411007510" target="_blank" >http://ac.els-cdn.com/S0277538711007510/1-s2.0-S0277538711007510-main.pdf?_tid=f290745e-7b5e-11e2-813b-00000aacb361&acdnat=1361366030_ee722d46031401e078f413732a8289f411007510</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2011.11.059" target="_blank" >10.1016/j.poly.2011.11.059</a>

Result language
angličtina
Original language name
Cisplatin and oxaliplatin derivatives involving 7-azaindole: Structural characterisations
Original language description
Platinum(II) dichlorido and oxalato (ox) complexes of the composition cis-[PtCl2(Haza)(2)] (I) and [Pt(ox) (Haza)(2)].H2O(II.H2O) were prepared by a one-step syntheses from K-2[PtCl4] and K-2[Pt(ox)(2)].2H2O, respectively (Haza symbolises 7-azaindole). The complexes were characterised by a set of spectroscopic methods (IR, Raman and multinuclear and 2D NMR), as well as by mass spectrometry, elemental (C, H, and N) and thermal (TG/DTA) analyses. Single-crystal X-ray analysis was performed for cis-[PtCl2(Haza)(2)].DMF (I.DMF) and [Pt(ox)(Haza)(2)] (II), obtained by recrystallization of the complexes I and II center dot H2O from N,N'-dimethylformamide (DMF). Both complexes, of a square-planar geometry, involve a tetracoordinated central Pt(II) atom with two monodentate N7-coordinated 7-azaindole molecules in cis-positions, and with the coordination sphere completed by two chloride anions (I; PtN2Cl2 donor set) or one bidentate-coordinated oxalate dianion (II: PtN2O2 donor set). The comple
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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