Investigation of Magnetic Exchange Pathways in Heterotrinuclear Manganese(III) Schiff Base Complexes Involving Tetrathiocyanidoplatinate(II) Bridges
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F13%3A33145824" target="_blank" >RIV/61989592:15310/13:33145824 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/ejic.201301031" target="_blank" >http://dx.doi.org/10.1002/ejic.201301031</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.201301031" target="_blank" >10.1002/ejic.201301031</a>
Alternative languages
Result language
angličtina
Original language name
Investigation of Magnetic Exchange Pathways in Heterotrinuclear Manganese(III) Schiff Base Complexes Involving Tetrathiocyanidoplatinate(II) Bridges
Original language description
The first heterotrinuclear manganese(III) Schiff base complexes involving tetrathiocyanidoplatinum(II) bridges with the general formula [{MnIII(L4)(Solv)}2{mý-PtII(SCN)4}] {for which L42- is a tetradentate dianionic Schiff base ligand; L412- = N,N-benzene-bis(salicylideneiminate) dianion (1a), L422- = N,N-ethylene-bis(salicylidenebenzeneiminate) dianion (1b), L432- = N,N-benzene-bis(4-aminodiethylenesalicylideneiminate) dianion (1c), and Solv = CH3OH (1a, 1b) or H2O (1c)} were synthesized and characterized. The two terminal [Mn(L4)(Solv)]+ subunits are covalently bridged by [Pt(SCN)4]2- moieties in a trans arrangement. The coordinated solvent (Solv) ligands form intermolecular hydrogen bonds with the phenolate oxygen atoms of the neighboring molecules,which results in supramolecular 1D chain structures. Extensive networks of weak noncovalent interactions stabilize the crystal structures of all the compounds; moreover, hydrogen bonding within the chains was identified as a dominant exc
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Journal of Inorganic Chemistry
ISSN
1434-1948
e-ISSN
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Volume of the periodical
2013
Issue of the periodical within the volume
33
Country of publishing house
DE - GERMANY
Number of pages
9
Pages from-to
5781-5789
UT code for WoS article
000326749100020
EID of the result in the Scopus database
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