Thermal decomposition of [Co(en)3][Fe(CN)6]?2H2O: Topotactic dehydration process, valence and spin exchange mechanism elucidation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F13%3A33145841" target="_blank" >RIV/61989592:15310/13:33145841 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1186/1752-153X-7-28" target="_blank" >http://dx.doi.org/10.1186/1752-153X-7-28</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1186/1752-153X-7-28" target="_blank" >10.1186/1752-153X-7-28</a>
Alternative languages
Result language
angličtina
Original language name
Thermal decomposition of [Co(en)3][Fe(CN)6]?2H2O: Topotactic dehydration process, valence and spin exchange mechanism elucidation
Original language description
The Prussian blue analogues represent well-known and extensively studied group of coordination species which has many remarkable applications due to their ion-exchange, electron transfer or magnetic properties. Among them, Co-Fe Prussian blue analogues have been extensively studied due to the photoinduced magnetization. Surprisingly, their suitability as precursors for solid-state synthesis of magnetic nanoparticles is almost unexplored. In this paper, the mechanism of thermal decomposition of [Co(en)3][Fe(CN)6] ? 2H2O (1a) is elucidated, including the topotactic dehydration, valence and spins exchange mechanisms suggestion and the formation of a mixture of CoFe2O4-Co3O4 (3:1) as final products of thermal degradation.
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistry Central Journal
ISSN
1752-153X
e-ISSN
—
Volume of the periodical
7
Issue of the periodical within the volume
28
Country of publishing house
GB - UNITED KINGDOM
Number of pages
18
Pages from-to
1-18
UT code for WoS article
000318288000001
EID of the result in the Scopus database
—