Cobalt(III) Schiff-base cyanido complex usable as a ligand in preparation of heterobimetallic Co(III)-Fe(III) building blocks

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F13%3A33145855" target="_blank" >RIV/61989592:15310/13:33145855 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.inoche.2013.05.026" target="_blank" >http://dx.doi.org/10.1016/j.inoche.2013.05.026</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.inoche.2013.05.026" target="_blank" >10.1016/j.inoche.2013.05.026</a>

Result language
angličtina
Original language name
Cobalt(III) Schiff-base cyanido complex usable as a ligand in preparation of heterobimetallic Co(III)-Fe(III) building blocks
Original language description
X-ray structure and magnetic properties of a novel dinuclear heterobimetallic CoIII-CN-FeIII compound of the composition [{Co(3EtO-L5)}(mý-CN){Fe(L4)(Cl)}] (2) is reported. Adjacent complex molecules are connected through intermolecular N?H???Cl hydrogenbonds into 1D supramolecular chains. Such a compound can be considered as a potential building block for the preparation of Prussian blue analogues of high nuclearity showing interesting magnetic properties.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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