Versatile coordination modes of bis[5-(2-pyridine-2-yl)-1,2,4-triazole-3-yl]alkanesin Cu(II) complexes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F14%3A33152631" target="_blank" >RIV/61989592:15310/14:33152631 - isvavai.cz</a>
Result on the web
<a href="http://pubs.rsc.org/en/content/articlepdf/2014/dt/c4dt00462k" target="_blank" >http://pubs.rsc.org/en/content/articlepdf/2014/dt/c4dt00462k</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c4dt00462k" target="_blank" >10.1039/c4dt00462k</a>

Result language
angličtina
Original language name
Versatile coordination modes of bis[5-(2-pyridine-2-yl)-1,2,4-triazole-3-yl]alkanesin Cu(II) complexes
Original language description
Nine new mononuclear and polynuclear Cu(II) complexes [Cu(H2L2)Cl]Cl3H(2)O (1), [Cu(H2L3) Cl] ClH2O ((2)), [Cu(H2L4) Cl] Cl 2.5H(2)O (3), [Cu-3((3)-L1) 2(H2O) 3](ClO4) 2 H2O (4), [Cu-4(-HL1) 4](ClO4) 8CH(3)OH 5H2O (5), [Cu-2(HL3) (2)](ClO4) 2 (2)H2O (6a), [Cu2(-HL3) 2](ClO4) 2H2O (6b), [Cu-2(-HL3)(L3) Cu(teta)](ClO4) 3 2H2O (7) and [Cu-2(H2L3) (2)(ox)](ClO4) (2) 2H2O 2MeOH (8) containing [5-(2-pyridine-2-yl)-1,2,4-triazole-3-yl] alkanes (H2Ln, n = 1-4) in combination with other ligands, such as chlorido, aqua, triethylenetetramine (teta) and/ or oxalato (ox2-), were synthesized and characterized by various techniques such as elemental analysis, FTIR, NMR and UV-Vis spectroscopy. X-ray structures of H2L3 and H2L4 as well as complexes 1-8 were determined. The X-ray structures revealed that relatively small composition and structural changes in the H2Ln ligands have a substantial impact on the coordination geometries of the complexes themselves as well as on their resulting magnetic prope
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)