Ring Contraction of 2,5-Dihydrobenzo[f][1,2,5]thiadiazepine 1,1-Dioxides: Access to 4H-Benzo[b][1,4]thiazine 1,1-Dioxides

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F15%3A33156134" target="_blank" >RIV/61989592:15310/15:33156134 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15110/15:33156134
Result on the web
<a href="http://pubs.acs.org/doi/pdf/10.1021/jo502713k" target="_blank" >http://pubs.acs.org/doi/pdf/10.1021/jo502713k</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/jo502713k" target="_blank" >10.1021/jo502713k</a>

Result language
angličtina
Original language name
Ring Contraction of 2,5-Dihydrobenzo[f][1,2,5]thiadiazepine 1,1-Dioxides: Access to 4H-Benzo[b][1,4]thiazine 1,1-Dioxides
Original language description
Article reports an efficient synthesis of 4H-benzo[b]thiazine 1,1-dioxides via unprecedented ring contraction of 2,5-dihydrobenzo[f ]thiadiazepine 1,1-dioxides under mild conditions involving carbonMINUS SIGN sulfur bond formation. 2,5- Dihydrobenzo[f ]thiadiazepine 1,1-dioxides are easily accessible from commercially available building blocks, including Fmoc-protected amino acids, 2-nitrobenzenesulfonyl chlorides, and bromo ketones. Benzothiazine 1,1-dioxides represent pharmacologically relevant derivatives with biological, medicinal, and industrial applications.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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