Structural characterization of ferromagnetic bridged-acetato and -dichlorido copper(II) complexes based on bicompartmental 4-t-butylphenol

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F15%3A33156301" target="_blank" >RIV/61989592:15310/15:33156301 - isvavai.cz</a>
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S1387700315300228" target="_blank" >http://www.sciencedirect.com/science/article/pii/S1387700315300228</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.inoche.2015.07.010" target="_blank" >10.1016/j.inoche.2015.07.010</a>

Result language
angličtina
Original language name
Structural characterization of ferromagnetic bridged-acetato and -dichlorido copper(II) complexes based on bicompartmental 4-t-butylphenol
Original language description
The reaction of Cu(II) salts with 2,6-bis[bis(2-pyridylmethyl)aminomethyl]-4-t-butylphenol (Lt-Bu-OH) afforded two bridged-phenoxido/hydroxido complexes. The dinuclear bridged acetate species [Cu-2(mu-Lt-Bu-O) (mu-CH3COO)](PF6)(2) (1) and the 1D polymeric doubly-bridged-chlorido {[Cu-2(mu-Lt-Bu-OH)(mu-Cl)(2)](ClO4)(2).4H(2)O}n (2). The two complexes were structurally characterized. Both complexes revealed ferromagnetic interactions; moderate in complex 1 (J = +30.8 cm(-1)) and very weak (J = +2.25 cm(-1)) in 2.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/LO1305" target="_blank" >LO1305: Development of the center of advanced technologies and materials</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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