Electrochemical Oxidation of 2,4,6-Tribromophenol in Aqueous-Alcoholic Media

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F15%3A33156312" target="_blank" >RIV/61989592:15310/15:33156312 - isvavai.cz</a>
Result on the web
<a href="http://onlinelibrary.wiley.com/doi/10.1002/elan.201400412/full" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/elan.201400412/full</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/elan.201400412" target="_blank" >10.1002/elan.201400412</a>

Result language
angličtina
Original language name
Electrochemical Oxidation of 2,4,6-Tribromophenol in Aqueous-Alcoholic Media
Original language description
Electrooxidation of 2,4,6-tribromophenol on platinum gauze electrode in 90% (v/v) alcohol (methanol, ethanol, propan-1-ol, butan-1-ol) was studied. Products were investigated by gas chromatography/mass spectrometry. Structures of several different typesof monomeric as well as dimeric alkoxy derivatives have been suggested according to mass spectra of the detected products. Series of 2,6-dibromo-4-alkoxyphenols, 2,4,6-tribromo-6-alkoxycyclohexa-2,4-dien-1-ones and 2,6-dibromo-6-alkoxycyclohex-2-ene-1,4-diones were found. By analogy to identified monomeric alkoxy derivatives, a serie of dimeric 2,6-dibromo-4-(2,6-dibromo-4-alkoxyphenoxy)phenols was suggested and identified in respective chromatograms as well.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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