Magnetic coupling and relaxation in Fe[N(SiPh2Me)(2)](2) molecular magnet

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F17%3A73583032" target="_blank" >RIV/61989592:15310/17:73583032 - isvavai.cz</a>
Result on the web
<a href="https://link.springer.com/article/10.1007/s11224-016-0899-2" target="_blank" >https://link.springer.com/article/10.1007/s11224-016-0899-2</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s11224-016-0899-2" target="_blank" >10.1007/s11224-016-0899-2</a>

Result language
angličtina
Original language name
Magnetic coupling and relaxation in Fe[N(SiPh2Me)(2)](2) molecular magnet
Original language description
In Fe[N(SiPh2Me)(2)](2) molecular magnet, an extraordinary B ae 92 T hyperfine field was found in the 5 K Fe-57 Mossbauer spectrum under an external magnetic field of 0.1 T. This evidences the presence of an unquenched orbital angular moment at the central iron atom. Fe[N(SiPh2Me)(2)](2) complex is thus shown to represent a further example of low-coordinate iron complexes where quasi free-ion magnetism visualizes itself through an unquenched orbital moment. Magnetization measurements and hysteresis in magnetization indicated exchange coupling and nanosized magnetic units.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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