Visible light-mediated metal-free double bond deuteration of substituted phenylalkenes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F21%3A73608271" target="_blank" >RIV/61989592:15310/21:73608271 - isvavai.cz</a>
Result on the web
<a href="https://pubs.rsc.org/en/content/articlelanding/2021/GC/D0GC03081C" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2021/GC/D0GC03081C</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/D0GC03081C" target="_blank" >10.1039/D0GC03081C</a>
Alternative languages
Result language
angličtina
Original language name
Visible light-mediated metal-free double bond deuteration of substituted phenylalkenes
Original language description
arious bromophenylalkenes were reductively photodebrominated by using 1,3-dimethyl-2-phenyl-1H-benzo-[d]imidazoline (DMBI) and 9,10-dicyanoanthracene. With deuterated DMBI analogs (the most effective was DMBI-d11), satisfactory to excellent isotopic yields were obtained. DMBI-d11 could also be regenerated from the reaction mixtures with a recovery rate of up to 50%. The combination of the photodebromination reaction with conventional methods for bromoalkene synthesis enables sequential monodeuteration of a double bond without the necessity of a metal catalyst.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
—
Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
GREEN CHEMISTRY
ISSN
1463-9262
e-ISSN
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Volume of the periodical
23
Issue of the periodical within the volume
1
Country of publishing house
GB - UNITED KINGDOM
Number of pages
7
Pages from-to
440-446
UT code for WoS article
000608623000031
EID of the result in the Scopus database
2-s2.0-85099727606