Weak antiferromagnetic interaction in Cu(II) complex with semi-coordination exchange pathway
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F22%3A73615196" target="_blank" >RIV/61989592:15310/22:73615196 - isvavai.cz</a>
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S027753872200314X" target="_blank" >https://www.sciencedirect.com/science/article/pii/S027753872200314X</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2022.115962" target="_blank" >10.1016/j.poly.2022.115962</a>
Alternative languages
Result language
angličtina
Original language name
Weak antiferromagnetic interaction in Cu(II) complex with semi-coordination exchange pathway
Original language description
We present structural and magnetic studies of complex [Cu(dpt)(NCS)2], 1a, dpt = bis(3-aminopropyl)amine. A weak antiferromagnetic interaction mediated by a CuMIDLINE HORIZONTAL ELLIPSIS 7C non-covalent interaction was identified by magnetometry measurements, and the exchange magnitude (J = -2.24 cm-1, J stands for isotropic magnetic exchange constant) was determined. These results were supported by theoretical calculations (DFT) and the nature of the CuMIDLINE HORIZONTAL ELLIPSIS 7C interaction was studied by QT-AIM. It was confirmed that the CuMIDLINE HORIZONTAL ELLIPSIS 7C non-covalent interaction could be described as semi-coordination. The obtained results were compared to those previously reported for the isomorphous complex [Co(dpt)(NCS)2].
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
POLYHEDRON
ISSN
0277-5387
e-ISSN
1873-3719
Volume of the periodical
223
Issue of the periodical within the volume
SEP
Country of publishing house
GB - UNITED KINGDOM
Number of pages
9
Pages from-to
"115962-1"-"115962-9"
UT code for WoS article
000815786500009
EID of the result in the Scopus database
2-s2.0-85132729151