Synthesis and characterization of Cu(II), Co(II) and Ni(II) complexes of trithiocyanuric acid: The structure of {N,N '-bis(3-aminopropyl)-1,3-propane-diamine}-(trithiocyanurato)nickel(II)

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15410%2F03%3A00001410" target="_blank" >RIV/61989592:15410/03:00001410 - isvavai.cz</a>

Alternative codes found

RIV/61389030:_____/03:56033095 RIV/61989592:15410/03:00001413

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Synthesis and characterization of Cu(II), Co(II) and Ni(II) complexes of trithiocyanuric acid: The structure of {N,N '-bis(3-aminopropyl)-1,3-propane-diamine}-(trithiocyanurato)nickel(II)

Original language description

Copper, cobalt and nickel complexes with nitrogen donor ligands and trithiocyanurate dianion (ttcH(2-)) have been prepared and characterized by elemental analysis, electronic and EPR (copper complexes) spectra, and magnetic susceptibility measurements over the temperature range 78-291 K. Some of the complexes have also been studied by thermal analysis and by cycle voltammetry. Structures of the complexes have been proposed on the basis of magnetic and spectral properties. Two copper complexes of compositions Cu(bpy)(ttcH) and Cu(phen)(ttcH), where bpy=2,2'-bipyridine, phen=1,10-phenanthroline, are probably polymeric, whereas the copper complex with N,N-bis(3-aminopropyl)ethylenediamine (bapen) of composition [Cu(bapen)ttcH)](.)2H(2)O is mononuclear. Weassume distorted octahedral structures for nickel complexes, A single crystal X-ray analysis of [Ni(bappn)(ttcH)](.)5H(2)O shows that the central nickel atom is coordinated by tetradentate nitrogen ligand N,N'-bis(3-aminopropyl)-1,3-propa

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2003

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Coordination Chemistry

ISSN

0095-8972

e-ISSN

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Volume of the periodical

56

Issue of the periodical within the volume

1

Country of publishing house

GB - UNITED KINGDOM

Number of pages

11

Pages from-to

1-11

UT code for WoS article

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EID of the result in the Scopus database

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