Transition Metal-Free Sulfenylation of C−H Bonds for C−S Bond Formation in Recent Years: Mechanistic Approach and Promising Future
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15640%2F21%3A73612201" target="_blank" >RIV/61989592:15640/21:73612201 - isvavai.cz</a>
Result on the web
<a href="https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/slct.202102042" target="_blank" >https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/slct.202102042</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/slct.202102042" target="_blank" >10.1002/slct.202102042</a>
Alternative languages
Result language
angličtina
Original language name
Transition Metal-Free Sulfenylation of C−H Bonds for C−S Bond Formation in Recent Years: Mechanistic Approach and Promising Future
Original language description
Transition metal-free sulfenylation of C-H bonds for C-S bond formation has recently emerged as sustainable protocols for the functionalisation of various molecules. Researchers have extensively developed such protocols for the construction of biologically relevant sulfur scaffolds. There has been a gradual shift from metal-catalyzed to metal-free C-S bond formation methodologies, because the latter offer environmentally benign and inherently safe access to novel synthetic routes in organic chemistry. The present review offers a dynamic discussion on recent advances in transition metal-free C-S bond formation via C-H bond functionalization using different surrogate sulfenylating reagents. The review has comprehensively been devoted to radical and ionic mechanistic approaches. Some simple and eco-friendly reagents for sulfenylation viz. tertbutyl hydrogen peroxide (TBHP), hydrogen peroxide (H2O2), iodine/potassium persulphate (I-2/K2S2O8), inorganic bases, strong organic acids, iodine, I-2/triphenyl phosphine (PPh3), N-chlorosuccinamide (NCS), N-bromosuccinamide (NBS), potassium iodate (KIO3), I-2/bovine serum albumin (BSA), tetrabutyl ammonium iodide (TBAI)/HBr and graphene oxide along with their mechanistic approach has been detailed in this review. Moreover, modern methods for the C-S bond formation i. e., biocatalyst, electrochemical and visible light induced sulfenylation, and traditional sulfenylation methodologies have also been incorporated.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
21001 - Nano-materials (production and properties)
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ChemistrySelect
ISSN
2365-6549
e-ISSN
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Volume of the periodical
6
Issue of the periodical within the volume
46
Country of publishing house
DE - GERMANY
Number of pages
132
Pages from-to
13077-13208
UT code for WoS article
000729501700009
EID of the result in the Scopus database
2-s2.0-85120976276