Transition-Metal-Free Coupling Reaction of Dithiocarbamates with Indoles: C-S Bond Formation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F18%3A00490830" target="_blank" >RIV/61388963:_____/18:00490830 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/acs.joc.8b00206" target="_blank" >http://dx.doi.org/10.1021/acs.joc.8b00206</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.joc.8b00206" target="_blank" >10.1021/acs.joc.8b00206</a>
Alternative languages
Result language
angličtina
Original language name
Transition-Metal-Free Coupling Reaction of Dithiocarbamates with Indoles: C-S Bond Formation
Original language description
A one-pot three-component route for the direct introduction of dithiocarbamates into indoles using a C-H sulfenylation strategy mediated by molecular iodine is disclosed. Various indole derivatives including 1-methylindole, 2-methylindole, 3-methylindole, and 5-substituted indoles were applied successfully in this protocol to afford diverse indole-dithiocarbamates containing the dithiocarbamate group on the position two or three in good to high yields. The reactions do not require transition metals or disulfiram but use an environmentally benign solvent and simple commercially available starting materials.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Organic Chemistry
ISSN
0022-3263
e-ISSN
—
Volume of the periodical
83
Issue of the periodical within the volume
10
Country of publishing house
US - UNITED STATES
Number of pages
6
Pages from-to
5778-5783
UT code for WoS article
000432900800044
EID of the result in the Scopus database
2-s2.0-85047250370