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Unveiling the true band gap of fluorographene and its origins by teaming theory and experiment

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15640%2F22%3A73618661" target="_blank" >RIV/61989592:15640/22:73618661 - isvavai.cz</a>

  • Alternative codes found

    RIV/61989100:27740/22:10249752 RIV/61989100:27640/22:10249752

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S0169433222004172?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0169433222004172?via%3Dihub</a>

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Unveiling the true band gap of fluorographene and its origins by teaming theory and experiment

  • Original language description

    Fluorographene is a fully fluorinated derivative of graphene. Unlike graphene, fluorographene is a wide gap semiconductor/insulator that holds great potential for applications requiring two-dimensional dielectric nanomaterials. Despite growing interest and a well-defined structure, the basic questions of fluorographene&apos;s band gap nature and value remain a conundrum. Here, we resolve this long-standing issue, demonstrating a direct optical band gap at 5.75 eV by means of diffuse reflectance spectroscopy. The nature of the band gap and the factors contributing to earlier controversies are explained by combining spectroscopic methods, ab initio calculations based on the finite momentum Bethe-Salpeter equation, and structural characterization via x-ray diffraction and Raman scattering. Ab initio calculations complement the experimental results by showing an excitonic peak at 5.65 eV of a Frenkel exciton bound to a single atom. The calculations also reveal that the absorption bands at lower energies arise from the presence of fluorine vacancies in the material, which explains earlier controversies in the literature about the band gap of fluorographene

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    21001 - Nano-materials (production and properties)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2022

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    APPLIED SURFACE SCIENCE

  • ISSN

    0169-4332

  • e-ISSN

    1873-5584

  • Volume of the periodical

    587

  • Issue of the periodical within the volume

    June

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    7

  • Pages from-to

    "nečíslováno"

  • UT code for WoS article

    000776610200002

  • EID of the result in the Scopus database

    2-s2.0-85125638917