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Behavior of UV Sensitive Zinc Complexes Revealed by Using Electrochemistry and Spectroscopy

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62156489%3A43210%2F15%3A43907653" target="_blank" >RIV/62156489:43210/15:43907653 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216305:26620/15:PU113805

  • Result on the web

    <a href="http://www.electrochemsci.org/papers/vol10/100201696.pdf" target="_blank" >http://www.electrochemsci.org/papers/vol10/100201696.pdf</a>

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Behavior of UV Sensitive Zinc Complexes Revealed by Using Electrochemistry and Spectroscopy

  • Original language description

    Synthesis, electrochemistry and spectroscopic techniques for five zinc(II) coordination complexes with a combination of tetradentate amines 1,4-bis(3-aminopropyl) piperazine (bapi), triethylenetetramine (tet) and 1,1,4,7,10,10-hexamethyltriethylenetetramine (mtet) and thiodiacetic (tdaH(2)) or 1,3,5-benzenetricarboxylic acid (btcH(3)) are described. These complexes of general formulas [Zn-2(L)(2)(mu-tda)](ClO4)(2) and [Zn-3(L)(3)(mu-btc)](ClO4)(3), where L = bapi, tet, mtet, have been studied in water solution. Their stability has been studied by electrochemical methods (cyclic voltammetry and differential pulse voltammetry) by using the hanging mercury drop electrode. There were also studied interactions of zinc(II) complexes with UV radiation assessed by fluorescence spectroscopy. It was found out that three complexes (Zn-3(bapi)(3)(mu-btc)](ClO4)(3); Zn-3(tet)(3)(mu-btc)](ClO4)(3); Zn-3(mtet)(3)(mu-btc)](ClO4)(3)), after three minutes of UV irradiation became fluorescently active (l

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CG - Electrochemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/EE2.3.20.0148" target="_blank" >EE2.3.20.0148: International Cooperation in the Field of Nanotechnologies with In Vivo Imaging Techniques</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    International Journal of Electrochemical Science

  • ISSN

    1452-3981

  • e-ISSN

  • Volume of the periodical

    10

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    CS - SERBIA AND MONTENEGRO

  • Number of pages

    12

  • Pages from-to

    1696-1707

  • UT code for WoS article

    000348365800052

  • EID of the result in the Scopus database