Behavior of UV Sensitive Zinc Complexes Revealed by Using Electrochemistry and Spectroscopy
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62156489%3A43210%2F15%3A43907653" target="_blank" >RIV/62156489:43210/15:43907653 - isvavai.cz</a>
Alternative codes found
RIV/00216305:26620/15:PU113805
Result on the web
<a href="http://www.electrochemsci.org/papers/vol10/100201696.pdf" target="_blank" >http://www.electrochemsci.org/papers/vol10/100201696.pdf</a>
DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Behavior of UV Sensitive Zinc Complexes Revealed by Using Electrochemistry and Spectroscopy
Original language description
Synthesis, electrochemistry and spectroscopic techniques for five zinc(II) coordination complexes with a combination of tetradentate amines 1,4-bis(3-aminopropyl) piperazine (bapi), triethylenetetramine (tet) and 1,1,4,7,10,10-hexamethyltriethylenetetramine (mtet) and thiodiacetic (tdaH(2)) or 1,3,5-benzenetricarboxylic acid (btcH(3)) are described. These complexes of general formulas [Zn-2(L)(2)(mu-tda)](ClO4)(2) and [Zn-3(L)(3)(mu-btc)](ClO4)(3), where L = bapi, tet, mtet, have been studied in water solution. Their stability has been studied by electrochemical methods (cyclic voltammetry and differential pulse voltammetry) by using the hanging mercury drop electrode. There were also studied interactions of zinc(II) complexes with UV radiation assessed by fluorescence spectroscopy. It was found out that three complexes (Zn-3(bapi)(3)(mu-btc)](ClO4)(3); Zn-3(tet)(3)(mu-btc)](ClO4)(3); Zn-3(mtet)(3)(mu-btc)](ClO4)(3)), after three minutes of UV irradiation became fluorescently active (l
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/EE2.3.20.0148" target="_blank" >EE2.3.20.0148: International Cooperation in the Field of Nanotechnologies with In Vivo Imaging Techniques</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
International Journal of Electrochemical Science
ISSN
1452-3981
e-ISSN
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Volume of the periodical
10
Issue of the periodical within the volume
2
Country of publishing house
CS - SERBIA AND MONTENEGRO
Number of pages
12
Pages from-to
1696-1707
UT code for WoS article
000348365800052
EID of the result in the Scopus database
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