HDO catalysts for triglycerides conversion into pyrolysis and isomerization feedstock
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F14%3AGACR10CL" target="_blank" >RIV/62243136:_____/14:GACR10CL - isvavai.cz</a>
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S0016236113011514" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0016236113011514</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.fuel.2013.12.014" target="_blank" >10.1016/j.fuel.2013.12.014</a>
Alternative languages
Result language
čeština
Original language name
HDO catalysts for triglycerides conversion into pyrolysis and isomerization feedstock
Original language description
The effects of promoters, active metals and catalyst support material on deoxygenation of rapeseed oil were investigated. At 250 and 270 °C and various flow rates (W/F = 0.25, 0.50, 1.00 h), Ni-promoted catalysts were found more active than Co-promoted ones. NiMo catalyst was found as the most active metal combination, while CoW was the least active one. High selectivity for hydrodeoxygenation reaction pathway (total hydrogenation) was observed for CoMo type catalysts. Co addition into NiMo type catalyst resulted in conversion decrease, nevertheless selectivity was not affected. From the support-type point of view, alumina-supported NiMo was identified as the most active. SBA-15 support modified the product selectivity to increased formation of the hydrodeoxygenation products in comparison with the ordinary SiO2 support.
Czech name
HDO catalysts for triglycerides conversion into pyrolysis and isomerization feedstock
Czech description
The effects of promoters, active metals and catalyst support material on deoxygenation of rapeseed oil were investigated. At 250 and 270 °C and various flow rates (W/F = 0.25, 0.50, 1.00 h), Ni-promoted catalysts were found more active than Co-promoted ones. NiMo catalyst was found as the most active metal combination, while CoW was the least active one. High selectivity for hydrodeoxygenation reaction pathway (total hydrogenation) was observed for CoMo type catalysts. Co addition into NiMo type catalyst resulted in conversion decrease, nevertheless selectivity was not affected. From the support-type point of view, alumina-supported NiMo was identified as the most active. SBA-15 support modified the product selectivity to increased formation of the hydrodeoxygenation products in comparison with the ordinary SiO2 support.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Fuel
ISSN
0016-2361
e-ISSN
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Volume of the periodical
121
Issue of the periodical within the volume
1 April 2014
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
57-64
UT code for WoS article
000331542900007
EID of the result in the Scopus database
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