Self-sustained oscilations of temperature and conversion in a packed bed microreactor during 2-methylpropene (isobutene) hydrogenation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F62243136%3A_____%2F15%3AMSM14CL" target="_blank" >RIV/62243136:_____/15:MSM14CL - isvavai.cz</a>
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S0920586115002771" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0920586115002771</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.cattod.2015.04.036" target="_blank" >10.1016/j.cattod.2015.04.036</a>
Alternative languages
Result language
angličtina
Original language name
Self-sustained oscilations of temperature and conversion in a packed bed microreactor during 2-methylpropene (isobutene) hydrogenation
Original language description
Self-sustained spontaneous and reproducible oscillations of 2-methylpropeneconversion have been observed experimentally under certain conditions. The temperature of the catalystbed well reflected the oscillatory course of 2-methylpropene conversion. Theobserved oscillations exhib-ited exceptionally long periods ranging from 11 to 22 h depending on the prevailing space velocity. Theappearance of oscillations of the conversion has been ascribed to the complex interaction between theexothermic reaction, heat transfer and a reversible decrease in the catalyst activity. Possible mechanismsof temporary catalyst activity decrease have been proposed.
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CI - Industrial chemistry and chemical engineering
OECD FORD branch
—
Result continuities
Project
<a href="/en/project/ED2.1.00%2F03.0071" target="_blank" >ED2.1.00/03.0071: Unipetrol Centre of Research and Education</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Catalysis Today
ISSN
0920-5861
e-ISSN
—
Volume of the periodical
256
Issue of the periodical within the volume
2
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
11
Pages from-to
250-260
UT code for WoS article
—
EID of the result in the Scopus database
—