Induced Oscillatory Behaviour During 2-Methylpropene (Isobutene) Hydrogenation in a Packed Bed Microreactor.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F16%3A00468106" target="_blank" >RIV/67985858:_____/16:00468106 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0268242" target="_blank" >http://hdl.handle.net/11104/0268242</a>
DOI - Digital Object Identifier
—
Alternative languages
Result language
angličtina
Original language name
Induced Oscillatory Behaviour During 2-Methylpropene (Isobutene) Hydrogenation in a Packed Bed Microreactor.
Original language description
This contribution focuses on the induced oscillatory behaviour observed during the continuous hydrogenation of 2MP in a packed bed microreactor. Induced reproducible oscillations have been studied using the on-line gas chromatograph (GC-FID/TCD) and a catalyst bed temperature monitoring. Effects of the temperature, thermal conductivity and space velocity on the properties of induced oscillations have been investigated in detail. The study results revealed extremely high sensitivity of the oscillatory behaviour to the heat transfer conditions in the system. Experimental tests focusing on the space velocity effect revealed a significant influence on the oscillation amplitude height and period phase length with the high reaction rate. Based on the character of the induced oscillations, they have been classified as thermo-kinetic oscillations1 as they are resulting from the interaction between the exothermic reaction, heat transfer and a reversible decrease in the catalyst activity.
Czech name
—
Czech description
—
Classification
Type
D - Article in proceedings
CEP classification
—
OECD FORD branch
20402 - Chemical process engineering
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
Proceedings of the 4th International Conference on Chemical Technology
ISBN
978-80-86238-94-4
ISSN
2336-811X
e-ISSN
2336-8128
Number of pages
7
Pages from-to
45-51
Publisher name
Czech Society of Industrial Chemistry
Place of publication
Prague
Event location
Mikulov
Event date
Apr 25, 2016
Type of event by nationality
EUR - Evropská akce
UT code for WoS article
000579333500008