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Homogeneous and Light-Induced Nucleation of Sulfur Vapor-Diffusion Cloud Chamber Investigation of Constant Rate Supersaturation.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F01%3A27013051" target="_blank" >RIV/67985858:_____/01:27013051 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Homogeneous and Light-Induced Nucleation of Sulfur Vapor-Diffusion Cloud Chamber Investigation of Constant Rate Supersaturation.

  • Original language description

    Interesting results were obtained in the initial investigation of the nucleation behavior of supersaturated sulfur vapor up to temperatures above the transition. This is a second-order phase transition in liquid sulfur characterized by a change in molecular structure from closed sulfur rings to open radical chains within a narrow temperature range. Although the temperature dependence of the constant rate supersaturation is not correctly represented, it is surprising again how well classical nucleation theory describes experimental results even for such a complex substance. For homogeneous nucleation, there are indications that the gimel transition influences the nucleation behavior as a consequence of the changing thermophysical properties - density and surface tension - of the liquid sulfur. Photoinduced nucleation shows a striking effect directly correlated with the transition. Below the gimel temperature, the vapor is extremely sensitive to irradiation with light in the range 260-36

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA104%2F97%2F1198" target="_blank" >GA104/97/1198: Experimental study of the homogeneous nucleation kinetics in supersaturated vapors</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2001

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Physical Chemistry B

  • ISSN

    1089-5647

  • e-ISSN

  • Volume of the periodical

    105

  • Issue of the periodical within the volume

    47

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

    11754-11762

  • UT code for WoS article

  • EID of the result in the Scopus database