Laser-Induced Formation of Polymers from Unsaturated (Organyl)Trimethylsilanes in the Gas Phase.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F01%3A27013056" target="_blank" >RIV/67985858:_____/01:27013056 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Laser-Induced Formation of Polymers from Unsaturated (Organyl)Trimethylsilanes in the Gas Phase.

Original language description

ArF laser irradiation into gaseous trimethyl(propynyloxy) silane, trimethyl(ethenoxy)silane and trimethyl(ethynyl) silane results in chemical vapour deposition of thin films of solid organosilicon polymers. UV excitation of the two former compounds leadsto polymerization at the triple bond as a major process to yield respectively saturated poly(tri- methylsilyloxyhydrocarbon) and poly(trimethylsilylhydrocarbon), whereas that of the latter compound is controlled by cleavage reactions to afford poly(methylsiloxane). The processes represent a unique photopolymerization in the absence of photoinitiators.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CH - Nuclear and quantum chemistry, photo chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Polymer

ISSN

0032-3896

e-ISSN

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Volume of the periodical

42

Issue of the periodical within the volume

4

Country of publishing house

GB - UNITED KINGDOM

Number of pages

8

Pages from-to

1311-1318

UT code for WoS article

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EID of the result in the Scopus database

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