Isothermal Vapor-Liquid Equilibrium in the Quaternary Water + 2-Propanol + Acetic Acid + Isopropyl Acetate System with Chemical Reaction.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F01%3A27013107" target="_blank" >RIV/67985858:_____/01:27013107 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Isothermal Vapor-Liquid Equilibrium in the Quaternary Water + 2-Propanol + Acetic Acid + Isopropyl Acetate System with Chemical Reaction.

Original language description

Vapor-liquid equilibrium accompanied with chemical reaction in the quaternary water + 2-propanol + acetic acid + isopropyl acetate system was measured in a modified Dvorak and Boublik still. In total, 63 experimental points at 353.15 K and 16 points at 101.325 kPa were determined. The experimental data were correlated by means of the maximum likelihood procedure by using the NRTL model. Binary model parameters for the four nonreacting binary subsystems were obtained from available experimental vapor-liquid equilibrium data by using either the Hayden-OŽConnell or Marek-Standart correction as appropriate, to account for the nonideality of the vapor phase. NRTL parameters for the water + isopropyl acetate and 2-propanol + acetic acid systems were estimated from the global optimization based on the quaternary data. The results obtained from the correlation show a good agreement with experimental data. Three-dimensional phase diagrams for the quaternary system have been constructed and a po

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

<a href="/en/project/GA203%2F98%2F1446" target="_blank" >GA203/98/1446: Phase equilibria in systems with chemical reaction</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Chemical and Engineering Data

ISSN

0021-9568

e-ISSN

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Volume of the periodical

46

Issue of the periodical within the volume

2

Country of publishing house

US - UNITED STATES

Number of pages

6

Pages from-to

261-266

UT code for WoS article

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EID of the result in the Scopus database

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