The Synthesis of Rhodium Complexes with Cyclopentadienyl Ligands Containing Perfluoroalkyl Ponytails.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F01%3A27013213" target="_blank" >RIV/67985858:_____/01:27013213 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
The Synthesis of Rhodium Complexes with Cyclopentadienyl Ligands Containing Perfluoroalkyl Ponytails.
Original language description
The synthesis of complexes, which can be used as model compounds for catalysis in fluorous biphase systems, is reported. Modified cyclopentadienes of general formula C5Me4H(CnF2n+1) (n = 3,5,7,9), and their complexes with rhodium in two oxidation states:[RhCl2(C5Me4(CnF2n+1))]2 and Rh(CO)2(C5Me4(CnF2n+1)) were prepared. The electronic properties of the ligands and partition coefficients of all compounds synthesised in the system perfluor(methylcyclohexane)-toluene are reported, as well as the structures of isomers of the ligand precursors and the crystal structure of complex [RhCl2(C5Me4(C8F17))]2.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F99%2F0135" target="_blank" >GA203/99/0135: Transition metal complexes with cyclopentadienyl ligands for catalysis in fluorous biphase systems</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2001
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
Abstracts.
ISBN
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ISSN
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e-ISSN
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Number of pages
2
Pages from-to
39-40
Publisher name
N/A
Place of publication
N/A
Event location
Camerino [IT]
Event date
Sep 9, 2001
Type of event by nationality
EUR - Evropská akce
UT code for WoS article
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