IR Laser-Induced Thermolysis of (Chloromethyl)silane: Complex Reaction Involving H2Si:, H2C: and HClSi: Transients and Yielding Nanostructured Si/C/H Phases.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F02%3A27020225" target="_blank" >RIV/67985858:_____/02:27020225 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
IR Laser-Induced Thermolysis of (Chloromethyl)silane: Complex Reaction Involving H2Si:, H2C: and HClSi: Transients and Yielding Nanostructured Si/C/H Phases.
Original language description
Multi-pulse and single-pulse infrared laser induced thermolysis of gaseous (chloromethyl) silane, H3SiCH2Cl occurs via 1,1-HCl and H2C: elimination and dehydrogenation and yields nano-structured Si/C/H phases containing most of the Si and C atoms of theprecursor. The identification of final volatile products and observation of H2Si:, H2C: and HClSi: transients by LIF spectroscopy suggest that intermediate silene isomers decompose into silylene and carbene. The deposited films are composed of SiC and polycarbosilane and their H content differs depending on the mode of the IR thermolysis.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CH - Nuclear and quantum chemistry, photo chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA104%2F00%2F1294" target="_blank" >GA104/00/1294: Laser photochemistry of (chloromethyl)silane and silacyclo-pent-3-ene for chemical vapour deposition of Si/C/H and Si/H phases</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2002
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Materials Chemistry
ISSN
0959-9428
e-ISSN
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Volume of the periodical
12
Issue of the periodical within the volume
5
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
1519-1524
UT code for WoS article
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EID of the result in the Scopus database
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