Transient Detection in Infrared Multiphoton Decomposition of (Chloromethyl)silane and 1,3-Disilacyclobutane: Evidence for Cleavage of SiCH4 Intermediates.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F02%3A27020228" target="_blank" >RIV/67985858:_____/02:27020228 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Transient Detection in Infrared Multiphoton Decomposition of (Chloromethyl)silane and 1,3-Disilacyclobutane: Evidence for Cleavage of SiCH4 Intermediates.
Original language description
The transients produced in the infrared multiphoton decomposition (IRMPD) of (chloromethyl)silane HClSi:, H2Si: and H2C: and of 1,3-disilacyclobutane H2Si: and H2C: have been identified by laser-induced fluorescence (LIF). The nascent HClSi: and H2Si: populations are generated with a high degree of excitation and the species produced from (chloromethyl)silane possess more rotational and vibrational energy than those produced from 1,3-disilacyclobutane. The obtained quenching rate and radiative lifetimefor HClSi: are (4.6 0.3) 10-10?cm3 per molecule?s-1 and 369 10?ns, respectively. The formation of H2Si: and H2C: in IRMPD of both (chloromethyl)silane and 1,3-disilacyclobutane adds to previous knowledge on decomposition of (chloromethyl)silane and 1,3-disilacyclobutane and suggests that these transients are produced from the same SiCH4 (H3Si(H)C: and (CH3)HSi:) intermediates.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CH - Nuclear and quantum chemistry, photo chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/OC%20523.60" target="_blank" >OC 523.60: Laser CVD of naked and polymer-encapsulated nano-sized metal particles</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2002
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Photochemistry and Photobiology, A
ISSN
1010-6030
e-ISSN
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Volume of the periodical
152
Issue of the periodical within the volume
1-3
Country of publishing house
CH - SWITZERLAND
Number of pages
8
Pages from-to
17-24
UT code for WoS article
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EID of the result in the Scopus database
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