Synthesis, Fluorophilicities and Regioisomer Composition of Ferrocenes and Rhodium Complexes Based on Bis(polyfluoroalkylated) Cyclopentadienes.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F02%3A27020271" target="_blank" >RIV/67985858:_____/02:27020271 - isvavai.cz</a>

Alternative codes found

RIV/60461373:22310/02:00006491

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Synthesis, Fluorophilicities and Regioisomer Composition of Ferrocenes and Rhodium Complexes Based on Bis(polyfluoroalkylated) Cyclopentadienes.

Original language description

Ferrocenes and rhodium(I) carbonyl complexes were synthesized from lithium bis[2-(perfluoroalkyl)ethyl]cyclopentadienides and ferrous chloride-THF complex or tetracarbonyldichlorodirhodium. Fluorophilicities of starting bis[2-(perfluoroalkyl)ethyl]cyclopentadienes and ferrocenes made therefrom were determined. Four regioisomers of bis[2-(perfluoroalkyl)ethyl]cyclopentadienes, three regioisomers of the corresponding ferrocenes and two regioisomers of the corresponding rhodium complexes were identified and their ratio determined by 1D and 2D NMR spectroscopy.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

<a href="/en/project/GA203%2F99%2F0135" target="_blank" >GA203/99/0135: Transition metal complexes with cyclopentadienyl ligands for catalysis in fluorous biphase systems</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2002

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Tetrahedron

ISSN

0040-4020

e-ISSN

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Volume of the periodical

58

Issue of the periodical within the volume

20

Country of publishing house

GB - UNITED KINGDOM

Number of pages

8

Pages from-to

3847-3854

UT code for WoS article

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EID of the result in the Scopus database

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